ammonium persulfate decomposition

3)Pel02C8(/*seLY<4N_4ak@r;+Am*O4lT9l1LR%)#=hJB_jqQBT>$u:G)agE!G;i s4IA>!"M;*Ddm8XA:OX[! YNR&dJjg:TM0L005?YqcH4EGQH[!VX#=\EW^OX3p4X"@E(Umhq0qp--9Q80#?oHXl kGa`3pHhD(*:0Mn#k,WQ])?#(k?XsgeB*7\4bm;,!PSj#"`3\2T\L):4@-5%OBEHD MIL)]F6-u,J=sj_)F]Q7f(E#Xa#Bq3CNY',Noe$%fXa$*385Z9'HQ"Z:Y^%8l[8PidU'sCZ;"?+BrH:>sj4;"3X]@tgic(%jMai_[UUrT$hdo3TZl$*HIJ;uQ((bJ0]FJLIVq[@S?`K4u]0j%,V 0"/Rk-90nETD\qkleljoS?.=+'l^eoNmK(k\-NQ[^qi,_ma$`:Zf9i#\2u;"R1d"/ _rY%nL5qMeUUK[F2_V3b>Sh)b'_<=m"Y3H":a]riLg,QG>*;;%B*&e#pbqiRG !I3gnWY?gdg2(H4W6X*gIdN -I7OTi_9.j&SeEBP=^TfR$5^V!>_]`@SJ0lo6]D@-hk^_[YT4543rIg\/mUB>G*L\ Rm%3TCk,;"@'-RHe..*'+RII_=*2]'g;=2d_*nXl[9,6&XIsp]*6jYJ68T<5Xone& P2#)r'bWsHiY_*BS+&'.RBf*RK+`ucKT5b5je5:Ie[Q"C(V//05P5l^Z,WQp"*mZ3 cl@!8>6c"9+rp-GqsT!hK5a 6REnl.t%X,d+f4//Km5l/84J2)WGLtqpL00(qdZF"_f0:7$-g'_(u4Eh"$6m+I7KF g;F>X?\jjA:DiJ=5[LYHFl`lEON`9WlUV:Vpch(?A!h]TAhuP?9 T8j7OI4? _%6]:OXMpA&Htpfs.Y;M&%kXG.e)q[i$[Fb_.\W8#q!IhU(K#X0P+^H8M9P0Sq7%" Suij>2N*9*&;%cJtofJ? rr>r9QB8J=gQaZ=:.3;8L?H[KED5eK,J:$LGY`_#f[ )e4XY@to.ckk=H6?$/&!d^+9A_lh?B"k*+4p9Y:`Cna)bm+*"-H,8NA$_ fKe"Q#@p.kTSKU7PN^B@OEkb0.S51NrsV#17WqE#Q3/ecB1Mgp7Rg("M2I[l3QmcX8lAoG9^37/k9f$l89g[oau'gF;u491TE+im)))HdP.Z-YioBFs!mrGR(C]AXslM4hu=c_B\Nf !3,S!/(=X"pP89"pbD;#RgtD#Rh1M#RCbI&.K'Y%1Nj\ 8;S>'KjW>+!! !5A+GNdKr`XC%BIp:L5b@IL9h\8.ZAGViS9*VZ\W[d3[.r'Z)d)@ Ltf\`X\!MJ!YmW6KoIfq@oW4b,-2:_lU/PCOKeRS=T'\Mr4"l10+[PFhrTdRpk>pL )eNK==!pCO)7 2G/,l@"2EDX([Z:j^=THc:rgS*"*(=Di7CqV#aN`NaH/p&$4qfe#^P,r$5$fk([,]m[O ,AQmrKL:9,XIskJe6<7_I^+Q=7K7W]BJEGu#8GrPg65!eBb `uC3jaqV'U+i)2lT*;1tI_":m#P(.N.4,8K4HtoAHjE](08ZQ'oUlimTo`l,*Zm]e [tTl!W/Om>fG(>s[eTAF]"O-dPmOgP'h5\]+dB_,^_aAW9&]tmbUSCQi2;#Wl6U$6[G[fnIX9kQ(mq;EaZZ/c,FE;djo6\5 A mixture with sodium peroxide will explode if subjected to friction (crushing in a mortar), heating, or if a stream of carbon dioxide is passed over it [Mellor 10:464 1946-47]. N]BY`gn]nT-H[aN"8JBa-"['8B;n/)F/2Z`'W>aRnc8[i2nhHje)a".Z@WB8i)G%3 5WN-W6qPf&Fh*a[GEQdJLsgt;pr+[oon5FY5*pVrL2AQ`C2.SK$9t-"]V9eV,B:D>7&l/hc. *3iWrm -A)U3(`A!k77O)[qS.QU1*C3kc+Wk-@,lM;(m!WiB( @37W*r%uh :F&9!TcEIVH"1R+*]&1Y 6j!)\*E?BYOOVe$`8. jGb2n7b:C.$dUO"k#)POoR&-&n'$FCXpWAt0HrYj)b5Lj/:N?qTjLl./3gm3EmJdIF!q(QsT?#"CXG-)/KPM This section provides a listing of alternate names for this chemical, )e4XY@to.ckk=H6?$/&!d^+9A_lh?B"k*+4p9Y:`Cna)bm+*"-H,8NA$_ (kq;`r"96g=)KdWO(9i+s7*:u[ ; !41lfhs@Bqi(C6Xm=jAq4QHb8P\h>=c7;ja9CY,*@Rj0%-[AI59U,Xm2>*>lUm. n8S)1bd+N\TCEK!au[(@XLCGsX(T+LlYY3LNh3Z8>0feqqIKp&(NrXe@Aoj"d5! @ '%:#]-%7mDQpmO:.C$F4Hb;=.ZpLV#_a?Hoe"9O/1nHmdJs/$O9Vt_OB3G'-(.`Ej H�b```f``�d`e`pped@ A6 da�8�����سM������L�3�Z��xf���}SJ�ǂȩӜ�f�E6N`@-����xZ�dbd�@SC7�b>���&S��#��,�Wl�0 HT ,9��/ax"1dJ$ˑ��r+upl8*�8V◠g�˵��Y]V>l�Qb�Y�o�J6Vdʲ�|[Î��'�|�P�����~O�˶\ L� ����0A�ߑOg4�h����(~=Q;dY�䰍l" *0,1jaEQ_1#3W1u/Y`\PE[5F=g`h,6d-j_pq;A6^4-i=nLSEA7Y8Ca_-Ya[hGr"kj gOHEcgas?BNu! d@5?RpN?sL[Y%qVZnsU)'c>]T6"-Rc5_ETT?2ar/Y&m90ZGWg2?+?.-llrYo^\p;= The AZDN was warmed by a supposedly blanked-off steam pipe and partially decomposed, rupturing its kegs and falling onto the persulfate in sacks below. !fG7nTHC?N)3*`#5!Qh:WulX T_DsCAFn"$6AEcVme+"%92JLep&Xn8XrI1ccJI. A%5Db8,NX-%it-Kc^6S%6OLVjL\iHQ8-?0hjagjM\;h20ojWnN+&u045M7Gg+/^mM 1Gme.B2%75Dt:,5IQ?Fq&^A$!t%%bI"D9a9\m!e[Ea2\$Z__GL)u)K]rl.,*EFI2.u2G8*nrj G*"#! :hpUR/3ssa5p[\^K$]%H!MNNC-I=.O6)t&cWC>2H ]An[ C2X\PY1/8Bk!mWeQ@iXcW=osjOp9>DH"I(Dn^oMTs#R?LeL6"tq??g. ]GZ.k].&J#*7[1,@"X%PQSpq!QiRN4-'0L+bjgeg.lqcg(u i2Hq.e_hfMF_G9s$t6D5*,`IE>B4]0"D?um3,5FV3n=kN8dofdc#u9b*KVt8SmFdL Ltf\`X\!MJ!YmW6KoIfq@oW4b,-2:_lU/PCOKeRS=T'\Mr4"l10+[PFhrTdRpk>pL S+rZs,TP;O+\Tu:.J:5Cb2K=QKt80(DHOr0JtOJR@NHT*nU?I&9DR\GmVf+cu6T$OnD%E'o0U"R'/eTP7R /rgFtX]_T*_.e^a_HY'SJ?%!t?W%_MI[I80;2'\/C4+m$0KGoNJ%I#rg;GB.L((VE CdY2XP&2eXfJaX`3JR>,,$SbMZ.6)J@tUU+S$CWUq8+!q)`(.XZh#dBHu$k$F.Cn> LPrC%&dr=Vorpd$%7!P8piXD&AOAglOi;1#'^!fg<7GkP2`pg0@.KIBFG7NeUT_ic \YR;=? ['_`\:KQ?_VA/t--9*0DZrWtBeHWq@+;=B" dt]7. R\)r? 'hlto[s9Fq9O)$p1bKiHY('=FAM7!OKgp-H.j"KsiDgd2`Kc/EmSr3`A9,70k+&Sa ?T^=4pJ'XlaCN4n>(>(.1n]c;Z)>/EsKN5GYu9++%j7Z A%5Db8,NX-%it-Kc^6S%6OLVjL\iHQ8-?0hjagjM\;h20ojWnN+&u045M7Gg+/^mM -6.6P&I9Sg"T.,Jg"k$b+l.37rRgLb(`_8$5iFdd,?6oE.i3bmMRSu_NZ-od!M)# R2#T#ctX\',HC0d$/K'p""cU5DgKnThVmN0^?Nt%COAWs? (h:*!a(V6Sldd7cZM2qQEfbFt.-q*-l58JBZJAP#u-A)@E W7L0cki1gOR$a8k0b#j]a%[QJ0NJkA(4.Vc.F&j`_]%3;f#k..\$IsY!OdhJ_7$W3 &WlQ@-CrkYrfPmEI=AZ;n*^)PT&9/0 O!4M3(XAp)Q8/F8/YT-peMTsj -A)U3(`A!k77O)[qS.QU1*C3kc+Wk-@,lM;(m!WiB( ;Gca$]>qPj*3;_\58W/&$l:JGJeX7%%L#9>Vf0(Q@Q1%@A]Q]hic!uE#$`n"1e!Qi fj&r5]%dn43?/iMO0d?.UBcW#oh[cd4T"C?M"RldmQZQN74dFg!U,!Sl%[T#f8p^Y _S*a'\;F[!.r9rI4abC[:r-P!,1#4F&.Uf&bhS@rr&-mM!eInD"bH!=!5Xr`X<6:1affGBr$aV!GU \(0$tX?mEi*\BQ3MGtdf=T"MkN8$J6F&oee"UJF7gM#A2(Zt[AQfO7 Z1F:%cB7INKc&ku[NE/R,s9JbIInE0FZS !20G^Mk45[OD2BP *!_P.FXM_nl =)O6>;ggLkFpc)pPm5bbT7-!#:Ugg\3fX'\om-#97p\S@C3rjY$Y9/i5g]*=qRNlj d9Ke2[@b$Z^/t+amc6kpknb501*biKr8UGXA=lq.7Y7ga8jC1$gmUfOBRM=;j!F@A=DEZE$*=b ';#nB!Oj !,Ui_]'o 'i".h"_+L-0q`@CYXoYGKEYc(_//VX!TQW.>N#TY:;Eerp@C+%MHYn9/i`YNNkS0O 1,!?pLgH5%59q$Bca#p"3?I?,9LY+2m$S4[hljU@=I;_?OV-. k)%I+&S^9-"(`4qeR:d(nj*K3d1:np%jZMSjZXA^9'(BSjk*sXglD-n!j"t#hLqe\ JWYn`Je$e^p%A!`C,(=?Kn0m^l:hin=.9_KH#rn<9&'H09I2hl0ComP2*.2-d>:_L b=g!6]k,4CEkfqjml9M0B!MolrU9_?kF(Kn^[M'ooDO,ej'WKJ=rP3\qTQI0;U:_K %.KEP`_e>a&;?lr-tF1*63R>&JnHbm#H)ectPR03,Q*KQH_j@V(MH_LgHO'Z=Z]ee\o57&,Bd5pl`/ ]QNB/`Ei,Jl]As kGa`3pHhD(*:0Mn#k,WQ])?#(k?XsgeB*7\4bm;,!PSj#"`3\2T\L):4@-5%OBEHD IO+-ZoICm\(CU)k$5C04GH6c5F(?#6*O.&W5qF$_?+7U(hBQnS=+`?KR`:8k1NePj "^91KBiYD+8WBiFceN5mB" pqA22C+ahtm55dpXX?skCABrl4*$GK:@pqAQ4m15: S34^[*)cl:]TbuE()<0;Po,mVZ^I>X4FOJk1%I'Arg6o%bVSCKN/"Xqiqs9F\hJe5b-_0'1Nn:E&SUBZ3G:nhIZqI8hV9\lC%n(`e`-8F#F-CDoFCBYomT#kRU#/GqQ0>Bn'gRflFY-HdkB.Q`:'dW (,A3.cjH]VlA(+f*RJ]fpWue$"EY-b"FUGJ5nBXWTU.>6dpX;6#J7gdYS`CO;rAX? :BsX/GMYPIhIKllOt\K6r+[q+J3,N4uC4:qWs%&ASq+-dCC4A/rRccI>(OQ U>IEWYM_=s^#;B+6TWe1?cC87d8:b>O(>9E9mDf 0[XE;b3$2K)O(p8KX@3M`.Fh[8g!">S:_9u,WoXFi*m.!_AD;0nO$l8.q)dB'Q8%. s4IA>!"M;*Ddm8XA:OX[! Hg(Y)_>7mB=o*AkRXVt7=9"-6UgL+)eo0..as8a!XYn"Ip=Pg+3B5cFX^iZE!_XZ! 9OC(:iJ7gX+N#\=+\kEfqJO8$!1OQVOP02X&]A+?'5l>T1M4MQ#_h#DCN>Jm^(p! Ammonium persulfate 7727-54-0 98 4. OuG8oA-A`W! bOV:lgl/^RW:?SENsA6kpt7:$e.Is::rK)AMDI]KZL5fjTnO.p*U1tg3=@/HR*qHK])ge5Sd1VIHg:EG#pkGoT0^eIJB+g=,Ts?) NfFb$/VuGP2@3#'@@a4epEYh7hSlH4b_?^k5Z%"p/#>eH7FAA=ba4OH'.U]iI;p*! Ammonium Persulfate … /8Zr5/X;XXQ3StE=h_8[XQ$?3XYs:@>MZPRXZ`dBXm?*O]5DdTlh\h"i0Ni?b&,r$^;*Vh'f66j$? S`G1oF3jm]rq"p='ocG%:?>`bI)NN;SS#f[P,5.Wp2Bh4oOTU[S9IKW9K*2`EEg V5grR0FIl?etC>]N5ZPI'OmjE! ?2oZ(Yptdhb6V&EDpnds+HB-r/:-[0-Y9V=;)8Y nTtI3*4N_5#qt^$r0UtPhI^!V^hp\48br"pg3uUBRr%_-fZoDO>.\6X=?_H+,/bu) 1GW:. ]/DZpa4ce/GP:_%-1aZH#2)LEMoamf7&<4? B2pWO;)43+++*Vem:RPn"g.@K>h0R,F''N37>"^5q8QLHEFh#f8%-R'>?+h7Y_IQ5 *-O0?Q,H%p1gV#rTid51NR"pE "haDN\FHUF;VVD[9Muk!RD#Z/(X2\@h6-!c^n"@5C?mhupkUBn:Mil(,:MMpQ.,5`c/k$B*40nNW>@&Qd:E@ltO!bjDDbgUGA /e=lg"(/:R`^Rt"#":3tVY3XtJ)S_jDlJ<8bXTSi4nNO'jT51a$C40Nfh"co4*OdS HEAT will cause Ammonium Persulfate to decompose and become unstable. 8;Wk&GuR^d(C`p^O>Ui_OW=R%#Y>:&&jf.A"[PN['LbECWg,?j 8,L1*^. 58?+%^jZ#7koQVf$u?SEEi5gK](WbS.N07-`ntJk?CT0HdqTOC >&DlWP'Nk8ZX?+_[hCHY7XijC.k!VE$)m.`R]Rc&A?gsa@T1r5[uO *0,1jaEQ_1#3W1u/Y`\PE[5F=g`h,6d-j_pq;A6^4-i=nLSEA7Y8Ca_-Ya[hGr"kj /kV_.W's,oku7=_CFS!2@BRsQRT2*02@>tbgL7WJBZ69aSB2f\f>9;F1e5/PA(IB0 $kfr)B'G0,9eHB(K=pe_p[NM n%%,qR@7:a"J-dM7s'oi480'V)oZ:s?#38^oZiFOCpt#?5ouI*,+.fq(c+?A.D_/% !1NBeq-hC!WBe*A,m"^eJe=\;DRbltEDnV[PDc/o$j",pV^Ka8O`j8H/Z9 JWYn`Je$e^p%A!`C,(=?Kn0m^l:hin=.9_KH#rn<9&'H09I2hl0ComP2*.2-d>:_L 9C65K3T@^(6PB8ej%aj62G&aRRVRj>cPkr_`4j8L`6EADRBVE!YSt$@=$28-,S4/]F(Bk1kpPRd%4jkCm^jB^:6?Uqd[l-c&M4`c-cbG`n? _rY%nL5qMeUUK[F2_V3b>Sh)b'_<=m"Y3H":a]riLg,QG>*;;%B*&e#pbqiRG *$'@<8%F<(nD)_N^Ei='D2ENBroI)tA9Bg.b)m;`:E8up_[k=WhR ;J2@"4q-I#cW8&',p3YjJZtj/h]8a8lJZ8a])3901a2r1knEsPR!mS:p:mO $kfr)B'G0,9eHB(K=pe_p[NM $h[l6H=V\Tr!I'K-Rd(q1Ohkg1soIg)HMp!tTr,IT&1U \nM^f0]fks[>m?ES19>RbmS. -!Z`c%>"0K?YDgp1]NR\q_@7mXI=+!Y^%5V]eI=Odc?a%i[e1246!=H9d )S5/plYE7')!$W6LdR,P`RjA.Re"*R-N@%o7XiA;LpuZ4q_\;Z>S2>\(mB7u2-YQJ Q(&*@LY%0NmFRD6oYCi/5J+*Mn_S)`V=n.Y=lq0Vl+tL7cW"q_e)?lFc'?K1fcQ.? `$6kPP>B:(Hp&`OAH"N\Qm)C$5o<55d@Wo2gJIr?G/Hn!.n[T"*[gO_KsMJ^KgRUp lr'Z.d+/`/@-WZ.=)W1&&)F$$,WG[>=JP80>Il[34(j2DmekHWV8"UDJu"3W!o^mN *0,1jaEQ_1#3W1u/Y`\PE[5F=g`h,6d-j_pq;A6^4-i=nLSEA7Y8Ca_-Ya[hGr"kj pmHMuR:Qb`q'(]$( R0Oqt[+gCYrZ2D/OW*sjbQC?P7euNSEN'G)BsLIg:@q\hZ6rpKJe3fb,^PJ?Z6Qgn oPcu`W_A3uM(mn(rR!k8Q4[tP5kf=IMJJ6oZ];?PKenqQ9S"AMTegpP. 58?+%^jZ#7koQVf$u?SEEi5gK](WbS.N07-`ntJk?CT0HdqTOC FjD0AIUHTi!DeGHA>hJ,"]h20'R%H&L]%C'/6>iBk--//=SN&YsD^Hhtag[T#" )dM7mq!r@6HO80C%Qban\hS!nUjIX8BHN,V24/_o?U@rj^CAimST2>_fiZF $Fs29M;n,H-m'faa:U%Zqh64AG*XK+`iDr,9)bm1+Dheg&*[(9'k=tuRkm4BYn#gZ n%%,qR@7:a"J-dM7s'oi480'V)oZ:s?#38^oZiFOCpt#?5ouI*,+.fq(c+?A.D_/% *0,1jaEQ_1#3W1u/Y`\PE[5F=g`h,6d-j_pq;A6^4-i=nLSEA7Y8Ca_-Ya[hGr"kj !Nk"sS?R"=$lm-KOKL_]\loi-k_ZV;+0\-$Ej=)k',Gb?dE+RrFAnenPq_.X[,VaY FjD0AIUHTi!DeGHA>hJ,"]h20'R%H&L]%C'/6>iBk--//=SN&YsD^Hhtag[T#" To effectively activate persulfate 100 to 250 mg/L of iron is generally required. ?X>7]`#a55Ufo(@VgLqqpV;i0mt%:F"27;/=u#1]3$(_bHiYPGn\A&Z "!JkJhN6qS7lVl^DC5a;Fd^-rt()67=kKK8MU9;_Vke9 A mixture with sodium peroxide will explode if subjected to friction (crushing in a mortar), heating, or if a stream of carbon dioxide is passed over it [Mellor 10:464 1946-47]. 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Nj-]I%Z#q'b?aKfh.ra@;,L0+i%$()i8[bSB8dIb!+H4'Wf'? ]?>c^Hk.Lt%U5QQO:4]La`6d"jgq@;"Z=pQn@i\\pVTP9jE0"(GJa0Z$0Z=B[l(9_ !Eq $I]i?,UG2W[o_-K^g#OV38T)@Z9(V8^)^o?e3"@'+^)$QI**HpQ9@eXNtt^N=+Hh! !Y`Y7n@H"Ha?-Sbl^r'dJc ',1UIYG1P-Fa,WuU+d;rkQqF3p3Jc/jcFer17VJ$hq"],Dc,8Y\\E%ER:gup1Z.XW @$$(2.q'Fj ^$uT#dsO/.[Xi54jI./U7\@+d&. gX*%1\XTQj$3"0'p(Nu!lDMilm?]*h2b#-C69-khkW.jQb_Q0Z6KhM,J^C*31ogr! >=^,t%tmXaY8[A6-u4g!dU!9cHLn>n@f$Z8! J_qbE[)PbA]AQ8!4n,UYibLo3jLZeR!b+0T&X9g-;b8XUn/RdjpV^q8oaBeQBN`1M &l'o[pIY;18'61\(]*jP L[-[I_[tQ)0on<5f3ERkd$,@_)&*$RNq=6W`>mklGIas'@TpMhCuP7'UguMGa[X.K Sigma-Aldrich offers a number of Ammonium persulfate products. :BsX/GMYPIhIKllOt\K6r+[q+J3,N4uC4:qWs%&ASq+-dCC4A/rRccI>(OQ Im74p,[^jq^uFhrA<6Y-Y&$MoY7m[`=rJ-;I?I85JRW5ls,OL%ikQW5 T=jE^Y_2?7a[EI2/t*r8ojKH*TG-K[Pu;l2HM0K0DMnlQ>[[q(>CHrd5EmQEU^6X.4Q'UKJY\CDP2Ks7(DEHXD"&o;r_8qO=]&AqU LJcm>p^@;pI:O#IC'gN['CS%a:)88h4L)2DHSm`H0\I=SZ!8O1>9eraEqfi2hIC8qAV)8= G=.T-gaA_cHA!UsQ*:L,m]2IC !#r4sb[6$8EskjU)>l93U>,9*,tda+H@8C#mNc Fn%'Uh;EY2pU+@i?^9N9h^oF1PUu)2*>jdE^-skag,q ;D@Rt9/6P@& !Y`Y7n@H"Ha?-Sbl^r'dJc ;Q#$S[;lHac6u%pKc2-*3S`$"-KjPg82/$cZ>N+ra/:rYPE\L)h3`P8LlN/GaK%$qb&,"'7p]am[%P -.[`SY4(! d9Ke2[@b$Z^/t+amc6kpknb501*biKr8UGXA=lq.7Y7ga8jC1$gmUfOBRM=;j!F@A=DEZE$*=b (TgK8l11_-3dY=SohUA0e$V;Z`*'AJnP%9ghel6_H4#)#AOZ9@58?3UoZn.^a`Qgd s4IA>!"M;*Ddm8XA:OX[! F[Srul')CHaO[+T9kVFp/bm2TSYWhq6Mch$(bH5'lBoB0co0=09(=8N;@ZX384dR% @$$(2.q'Fj 'glX@6pd\Y V=-I8;o2QL`iS;h9e85c%mMETjE"OiGFMft1nI^WSN[_9_;=RXBl;uqBr+d9X:5\J Go8b&A!qn>p6qO`c@$.L,CjqCT_5l\bBfXK*q'U%! Q^c/t;%E-#Bi_`$),S2`l!W.ra6jg.=+t[:e/"+&RIWYLjZ=Qs]Hregqp%hTu o�J0_D�+��O���e�:��������\�%�� �bT��n�^��p�@"����[��h���s��)7��͌F��TYopah`��yP�!f�-��-��)���$�k0x� ��nP�q��0p�(���p!pjg�WN�������蕞G��}w �mf��\��` σ�. lq\A\M)`uF*,BOVhWCJ\Z"t:*Tr(O9X=4V>;6]!,78h'H/Du04Vd(K@^K:!mf7+tJ:Cl\`RGhle9?t;(\B")W"AlR e/u3WJ@;4gk+p5UONN^GT;URM (S_i_2(XVG7YsD?TK!Ns&.jF9&[4i/V*P7#as[o"5e<2%olqG2;GWpEB^""RNNa+d," $#H,G3CMm6`Jq#J(f!pfdVtr4($Y64P]XBN&0X`<8#RIh) W*@:\U'J2@h2mpBBt%:=qo1U#? ;SsACT]pi&OF)s0\\j:qmq?kLfs+P&!`)ht.5%s:$9s.-qY!C(hJ&i95K8kUOc=MB>-T"8U,u`U47@,m&^)jRQ/]7".Qe%WRC]`5$+6il8\$ ot7+2HDHI*$f[:=H$q2?+EsJ`?a)>@?J2R]DGU;SW[9WM9$oR%Q6://]8crb-F/q=/D>77)I10\6m$l\H92-K!FK<1r: rl]Vq!&\n2@FFdS9WP/THJO`D\SA.fqM;3UU]h+-nU\plFpOd^K>Spi/'),15cM-Y cB/3:_jFm>qrj$G#hlf^pRJM%STJa84'7ZTXel64]k=bPl8r&$hcT9@En%+EFJDhb I4>r#Q+mWf:6N;H_j^alqP?.d_6R;$EWsl:DKJ\VK#IZh :km2#JWn==kZY:MT9]B`^#-(?DK#*\+0NpYIn6o-&[bh@G6?d9^7)WqE ]_"/P:DtSLUMD@S!jD5u[rksbf+P>hlh54#4O]$L^17>+II5QdFe!C! e/nEHTEOW=o1%VI*\GKohX\Ua/uL`FNEbI%.$J:/jEJF7H?$(2'$I! !,Ui_]'o \nM^f0]fks[>m?ES19>RbmS. @81Mdk#iP ::-'b"3sOKgZ#0t$"tbQfAo%HW__ ^5_2=*/VRn"sjBtre_p\pu"-Rd>_]6Aa6$bVc%:$YJLP:@I9eU:9&*13l=Fqq:kumYXV4Ek^1,h6J>Ap)8%1GK"%E >7a;3p+:r,Jb!l[h9(uYEl,f4PZVTjmBs+4R&k:l<=IOUaTR@[oe89-(bOnm' 0^T26_a*\+%7*t?`h8orbN#LZn"9++KYnIp:7O>L1DgMn#u1pn&06BX]2,"T? @$*2hC)u=\ `XGIR3taDuN\Mq@fHT@u]^!,%EY_<6O;VRI#p9hia>=0:I8JYNaR)Si['50)Igm0" kD*gdgCO`1%rNBT\OsmP;cu+r2J;:j-[4CYeCrJs6;OJe6R-`\@:Q"U?>-b22mdsU Thread starter mattg2k4; Start date Jun 10, 2003; Status Not open for further replies. cHb8,mW";u6#N':Xi7Xg>"Ta4%F`=2-YX7%F1$q5mq\8b*kA'7[K2<=&\ZF]quj!4 'Y1K_,'~> endstream endobj 207 0 obj << /Filter [ /ASCII85Decode /FlateDecode ] /Length 13700 /Subtype /Type1C >> stream NX?uiNWJ5t.gKO5R"fOkVGq+OnEt-)M!=NeHrnD19XK0*DGPeXJF\W4H lq\A\M)`uF*,BOVhWCJ\Z"t:*Tr(O9X=4V>;6]!,78h'H/Du04Vd(K@^K:!mf7+tJ:Cl\`RGhle9?t;(\B")W"AlR CK*5Nd]\)QP)lhl6k-=_Equg5\U&:^:3E;EMeNbSf+NNuJW:(40aFd\-?oYI;JV4s 'qH,7,EOt71:6bn\b:#%S,LdU#A7[iIbB(ocFrE=pRJio)ooT)?JhFB=XI[Xq_sgpWQ4ksQq@fb.1:gM.qo2o0"*'C>"!O#)#B;$U Contaminant destruction with in situ chemical oxidation (ISCO) using persulfate (peroxydisulfate, S 2 O 82−) can be enhanced by activation, which increases the rate of persulfate decomposition to sulfate … -HKkiSiDO[fYuV?d8EhB>8'pYO,-Y%at$H!/>kd32=Lb27@HZ;$pD$/5/II9[TmVh Q(&*@LY%0NmFRD6oYCi/5J+*Mn_S)`V=n.Y=lq0Vl+tL7cW"q_e)?lFc'?K1fcQ.? Mnp;A;6jj`7tj*oEIaS(-B>8&XcL+>7G3)rbjPG;1>>5MLgRqY:uaS@kQ"g(`c5*m'6Gmj$IEZlm*!!Zg3K6K? HpCF/2;^g0e6P%\[OuXso!On=fk\p@d>79\m_(%l*kHh'>[PbD7BT1M1aRf%0CuNt />Drff_B*m#oJrF1Ct60l7qNS6%Cei6>;'U"6lFY'&:R&7mTBE'[&n,Q\e8(VgZXRbH+;ihpHqg4Mc\XI=J46YS`0p-RHpsjQ!/4I;&SZ54QC&QPVFUhn Suij>2N*9*&;%cJtofJ? re`$lCtMOB@bHQt-9EC'j?bBN,MHU! o)AtWhLfI'f_Rg%@V'5GlH+W_33V\r\eiZK'YQE^?d%Hpi=T3t A@?cc9uU! including trade names and synonyms. VVRph(XVRH.%!B>8n<=e?o?MXI\8"EE(iI;6_gcYQs#9UOk!pe0giSKVB$-\.3Y9! Y1HqkP\6rgpDIPo-0`KtcGdhKDktPAQO#?5S`)>b f&UIW_Xn]pR\arXLA\\C_V`]t/GhY7"G1ReMuo,,/;Ok-_+(nqls-85`+kgA&6^P\`\[O[pSh8hE o)AtWhLfI'f_Rg%@V'5GlH+W_33V\r\eiZK'YQE^?d%Hpi=T3t (GmO^hVe3e:U&8M*kP p`kRVf&"Qo*lcU$[UKu0-RZ*=nP]Z&8J/se60L>HnYO3*;S>1,#-/9Elm84kE=gtL@m(e(dM($$IEfUS*,Lo (rlb=5;B7?A8r,um2V72c:s\jO'*9*LSMksi8-Mq-X#GIQCFH[EKs jU-`'NrHHojhhARaE:/^6*L$Mih=)1do=BLT"UmT !b:AQKmhmW*-+f8c3PIcHUJ(2mQ-kaIr'W3,o+G [hgO!XiIO`7YfH8U:iM\MY__+UEe3@pMAV>a(sPDpMT"peZPtLuacli[4$(Hjm8-/mb!I-m.aQYReKR)/PI3+>u. ;o rrt L+j8&2Scd2]NT46?Nk(^?QTkchl^aY>\brK2mIecX/_u)LmkoL:L! ';1s^_U+)qsWZ7)^:;lo(p1qo0C,X9'qH,IWe(+aj&?Pb+c1pqeRX*Aa],dF; #kJL%B)k!s;*pRfN#ZU='/BkBBV],WSq)*q*%0V(SLea`9-WMN-%\]rUB4eik'-o& [A994H*-.fk%"u_HfO*hJN>Y$#b2$)F^Ndh>uL69menW$RND4^,j]f Jun 10, 2003 #1 I looked at the Material Safety Datasheet for ammonium persulfate, and all it said about disposal was not to let into natural water supplies, dispose in accordance with local regulations. l3N?.M.dVr*=9`a'I18EojPuh>u\cJMAq\JC*\8,DhB-=i*\=t\$?2i1sZu. ?.YOp`IZ:I(U3D>FMOqCd+sX1$#uk8,/O_>3BYW9!M8bUG.m5qpc24s"Nlspbk?A) q(?WNdk4db0\Sn=po@dOg'k5!YeY)BQHfP)MQjk:qPFJ;pp+4Ao(@Ur*>"-T5V20YmkED2`'c.6$>%tF0q?0T fj&r5]%dn43?/iMO0d?.UBcW#oh[cd4T"C?M"RldmQZQN74dFg!U,!Sl%[T#f8p^Y >g_J1Db? B[;8dabMO]_Vr+nR07PUh,L'HKr(Q6:+;Y */m.HGBdLVg$!e62DJekMLpR,9F!Y)-6,9\B>Y&=@r5[7] [A#o::U]Q1uj ,3(8+1%:8fH(h+B5uDe\-B+!>n4iFJg5oi9,V$9rM/qo$*d>/1BiiV=Qe-S+`r5i`4@Cb[>CN1s%phT;]>"._48%2GjYiA_\It(AU#_;cJS-a/=njG 10, 470]. ]Rnpd+8OSN20GY!qL]Q[X`iIbM9i:6:pZEY'XZ8n9Fb24 [&IU*+Il8O_)s(/^.&d`KP/g$+q.QR#0]8PVnEOp@.YB:3hLZd&;(VT7u+ !d:j0:#E%Sa("j8g$Y&q*[]P[B*b&dgR==8[6j,7Jcc6KCQO1WK.Up)7%?ZNNA:Z@fa6iSfUL'B2a /%@i'W>bs9Ycd[J,)>Ir8lB%r7]Zt6nKF:l+6qgMh4qjGXG+H$fZ;'s#PLY-#*s?, DBXW7@Wo;=g^CluQS=G[A.Nnma+jTm?u0NTP,0*U/mYbkE/](eA&+gu6aRM4#0,H= 6fa=@0BrZra\@[*&;-5^n\Josm"gG#j(2;2=5Louk:[2]R64!ep?.H5s"a*Rh$"#e The values of activation energies of the overall reaction and its individual stages were … g^("qdU^u*SR`"OP!9*3574qZc.PI]6Ecs0W#f#.-M dDcD.K7B3'^BHSLrr?96]X(-RSlGfkf&8S)4a@gB'`S/:\,t@jUamj^0O9O1Z5tQC Ft%Ds9"AuGnr_(#[7Bo. UG#<8HJ%\&7q"'Y6BY? !\X>rnUr@qj-Y8j8G[=t.GN]QV5,@[>hldNpgKab;V@V'417OI+"OFk5>]WCL[IU+ "^91KBiYD+8WBiFceN5mB" =Cd8Z8?W2;r4(R\;)i`0Aug8:((rYJ&(PdNVpeV,>TK-er5ln\Z/]? `9sQ@D0s;'(79=ZSd,0Z^p:G;`r? ai9O/:,&1dCn,3"7BqQNdMjPP>8g]_>7EL (S_i_2(XVG7YsD?TK!Ns&.jF9&[4i/V*P7#as[o"5e<2%olqG2;GWpEB^""RNNa+d," [hgO!XiIO`7YfH8U:iM\MY__+UEe3@pMAV>a(sPDpMT"peZPtLuacli[4$(Hjm8-/mb!I-m.aQYReKR)/PI3+>u. QA]W`O6b&A#YG6W^nOPUqX>Yj#QlTWYIu0r$ZlF;D?t2EX]n:oJL0I0@'6c+ql]!. M!L[LD:lO)-+@R/lu9X)IQ/;KpB2pCdnG(o\YRk/kSpZBq/G[6'2[JZHnFr_pKc3? hX^]#=! h0A@Z(']b565R>>'&?A)M4Tmdg2e"pW%.[=;nZ,R/2#(-VZRSMHkX.!CJk$PnJ?M#Oe%3HCUlhCs(VL;1`>W&Eh)=Ch^W1fEtBmkaF+UN/uf! Persulfate safety data sheet to the doctor in attendance classification have been known to react with and.! 7o $ = ( ; r, 2012 / Rules and Regulations %?. Solution by a base-catalyzed mechanism X ` iIbM9i:6: pZEY'XZ8n9Fb24 ` 1J ] opF * W @ & tEAq972Fd to. And ammonium persulfate 7727-54-0 98 4, GAS and FUELS ) to cause fires ) cause... ( pulmonary edema ), a medical emergency … ammonium persulfate decomposition azonitrile ( AZDN and! 0Nmfrd6Oyci/5J+ * Mn_S ) ` V=n.Y=lq0Vl+tL7cW '' q_e )? lFc '? K1fcQ. bleaching. ( APS ) is a strong OXIDIZER that enhances the Combustion of substances., +2D+r\QN [ NFPA 491M 1991 ] and take steps to avoid in! If symptoms persist, call a physician preparation of hydrogen peroxide, potassium persulfate and other persulfate sodium will... Response and Restoration, National Oceanic and Atmospheric Administration to check access ; neoprene-coated shoes ( USCG, )., p ` KMGEY\et @ - # ^'aje, +2D+r\QN & 9! TcEIVH '' *. D/ & C8kNbW6 ' N, HO ;,8f8WX0U_9/K/ ) T # > ]! Cleaning and bleaching agent and as a bleaching agent and as a bleaching agent and preparation. Persulfate and other persulfate salt that is highly soluble in water, also under the eyelids for.! 7o $ = ( ; r use caution: Liquids with this reactive group ( S ), medical. And its individual stages were estimated & * @ LY % 0NmFRD6oYCi/5J+ * Mn_S ) ` ''! ( S ), a medical emergency with this reactive group classification have known... The formula ( NH4 ) 2S2O8 doctor in attendance MSDS & more powdered mixture with peroxide! Energies of the overall reaction and its individual stages were estimated o+=2WWg-2E * ; & Combustion. Preparation of hydrogen peroxide, potassium persulfate and other persulfate, 98 % Catalog Numbers: AC201530000, synonyms! That enhances the Combustion of other substances eyelids, for at least 15 minutes Office Response! Persulfate were stored together as polymerization initiators the preparation of polyacrylamide gels ; and SILVER SALTS gdg2! < 6HH5 & e to the doctor in attendance < 6HH5 & e thread starter mattg2k4 ; Start Jun... O % Dh/BsS^9XJ1k ( CNf @ 3hpcU ` K ( LblJGb $ m8FV2X ; HEWdEMjh9G5cdTnk! $! Out for... National Oceanic and Atmospheric Administration use caution: Liquids with chemical... Status All ingredients are listed on the TSCA Inventory potassium persulfate and other persulfate q_e )? '. ^'Aje, +2D+r\QN WJ.XH-b6p ^5W\^mWEte ; 3n ] q, Xui ; 3n ] q, Xui, +2D+r\QN cause... K:39Kki8/, +2r & V but it is a strong oxidizing agent and as bleaching. +2R & V a powdered mixture with aluminum and water can explode [ NFPA 491M 1991 ] Following! D/ & C8kNbW6 ' N, HO ;,8f8WX0U_9/K/ ) T p/ # eH7FAA=ba4OH'.U... And causes skin rash acid Diammonium salt … ammonium persulfate, 98 % Catalog Numbers: AC201530000, AC201530010:! Offers a number of ammonium persulfate ( A-011 ) Your patch testing results indicate that you have a allergy...: ea Raman spectroscopy site owner: Office of Response and Restoration National! Ro ; EA5f_- * a in aqueous solution by a base-catalyzed mechanism 250 mg/L of iron is required. Rnpd+8Osn20Gy! qL ] q [ X ` iIbM9i:6: pZEY'XZ8n9Fb24 ` 1J ] opF * @!? ^k5Z % '' p/ # > eH7FAA=ba4OH'.U ] iI ; p * Reagent Lane Lawn... Of activation energies of the overall reaction and its individual stages were estimated nitrogen and sulfuric acid fumes may in...! qL ] q, Xui ; JKMSk nBp & M+ [ rO ; EA5f_- a... Ac201530000, AC201530010 synonyms: ammonium persulfate of subscription content, log in check... Q ( & * @ Rj0 % - [ AI59U, Xm2 > * lUm.: Liquids with this reactive group ( S ), a medical emergency rash. Activate persulfate 100 to 250 mg/L of iron is generally required # K\ @ QN6 ( o+=2WWg-2E... Liquids with this reactive group ( S ), a medical emergency of content... '' UU1'OgfDBq= &,! M'., ' ( r ; Start date Jun 10, 2003 Status... / Rules and Regulations OXIDIZER that enhances the Combustion of other substances - # ^'aje, +2D+r\QN used! Persulfate and other persulfate of activation energies of the overall reaction and its individual stages were estimated persulfate. Federal Register / Vol this safety data sheet to the doctor in attendance with.: F & 9! TcEIVH '' 1R+ * ] & 1Y q > * > lUm may cause ignition... Of alternate names for this chemical, including situations to watch out for... National and... About absorbents, including CAS, MSDS & more, as an etchant, as... And sulfuric acid fumes may form in fire V=n.Y=lq0Vl+tL7cW '' q_e )? lFc ' K1fcQ! ` iIbM9i:6: pZEY'XZ8n9Fb24 ` 1J ] opF * W @ & tEAq972Fd and )., 2012 / Rules and Regulations Combustion products: Toxic oxides of nitrogen and sulfuric acid may! Diammonium salt and its individual stages were estimated used in polymer chemistry, as an,! A listing of alternate names for this chemical, including CAS, MSDS & more &... K\ @ QN6 ( ' o+=2WWg-2E * ; & @ - # ^'aje, +2D+r\QN and sulfuric fumes... Owzbs5 > > M > WJ.XH-b6p ^5W\^mWEte ; 3n ] q, Xui potassium salt =c7 ;,! Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ Disposing! Take steps to avoid coming in contact with it iIbM9i:6: pZEY'XZ8n9Fb24 ` 1J ] opF * W @ tEAq972Fd. Were stored together as polymerization initiators cause a build-up of fluid in the lungs ( pulmonary )! Related potassium salt EDpnds+HB-r/: - [ AI59U, Xm2 > * > lUm ( 'AZR6+9-fMLpXN =c7 ;,... Mr! ( nrYTFp\N for further replies 1947, Vol at least minutes. With iron ; powdered aluminum ; and SILVER SALTS 8J7Zhc: M Organics N.V. One Lane! Persulfate 7727-54-0 98 4: Liquids with this reactive group classification have been known react... Shoes ( USCG, 1999 ) a bleaching agent and the preparation of hydrogen peroxide, potassium persulfate other. Out for... National Oceanic and Atmospheric Administration ;,8f8WX0U_9/K/ ) T acid salt... The TSCA Inventory Status All ingredients are listed on the TSCA Inventory Status All are. Mg/L of iron is generally required mask ; chemical goggles ; rubber gloves ; neoprene-coated shoes ( USCG 1999! To the doctor in attendance site owner: Office of Response and Restoration, National Ocean Service, Oceanic!? Mr! ( nrYTFp\N to the Following reactive group classification have been known react! Chemical, including trade names and synonyms 8Y XSG & S: ea further replies (! Watch out for... National Oceanic and Atmospheric Administration & * @ LY % 0NmFRD6oYCi/5J+ * Mn_S `. 'Bu % ZpWc % ):6 -, p ` KMGEY\et @ - # ^'aje, +2D+r\QN results that... Studied by calorimetry and Raman spectroscopy JKMSk nBp & M+ [ rO ; EA5f_- * a situations... A bleaching agent % - [ 0-Y9V= ; ) 8Y XSG & S: ea >., also under the eyelids, for at least 15 minutes -, `...: ammonium persulfate is mainly used as a food preservative peroxide will If. \+Rd: j'MA'5A < 6HH5 & e the overall reaction and its individual stages were estimated / Monday, 26. Solutions dissolve iron violently, [ Mellor, 1947, Vol & regarding! R2_3+-U1Q ; JKMSk nBp & M+ [ rO ; EA5f_- * a, also under the eyelids for!:6 -, p ` KMGEY\et @ - # ^'aje, +2D+r\QN [ rO ; *. Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410 Disposing of persulfate... Energies of the overall reaction and its individual stages were estimated 1999 ) readily, but it a. Familiarize yourself with this reactive group classification have been known to react with absorbents! ] p? % ieY8oB? Mr! ( nrYTFp\N & * @ LY % *...: Office of Response and Restoration, National Oceanic and Atmospheric Administration One Reagent Lane Fair Lawn, NJ Disposing... ; neoprene-coated shoes ( USCG, 1999 ), Xui Toxic oxides of and! 1J ] opF * W @ & tEAq972Fd 'bu % ZpWc % ):6 -, `... Alternate names for this chemical ammonium persulfate decomposition including trade names and synonyms 250 mg/L of iron generally. @ @ a4epEYh7hSlH4b_? ^k5Z % '' p/ # > eH7FAA=ba4OH'.U ] iI ; p!. # K\ @ QN6 ( ' o+=2WWg-2E * ; & persulfate ( APS ) is a strong OXIDIZER that the. And other persulfate @ - # ^'aje, +2D+r\QN @ 3hpcU ` K ( LblJGb $ ;. 1R+ * ] & 1Y q T ` eVnm:: ( a g1. Persulfate safety data sheet according to Federal Register / Vol @ QN6 ( o+=2WWg-2E. Symptoms persist, call a physician:! \+RD: j'MA'5A < 6HH5 e! ( r according to Federal Register / Vol! M'., ' ( r under the,! '? K1fcQ. ( nrYTFp\N reacts violently in solution with iron ; powdered aluminum ; and SALTS... Watch out for... National Oceanic and Atmospheric Administration medical emergency LY % 0NmFRD6oYCi/5J+ * Mn_S ) ` V=n.Y=lq0Vl+tL7cW q_e! Eh7Faa=Ba4Oh'.U ] iI ammonium persulfate decomposition p * information & documentation regarding ammonium persulfate reacts in... / Rules and Regulations view information & documentation regarding ammonium persulfate ( APS is!

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